I don't know if this is exactly what you need, but I've fixed your code.
Here you go:
<?php
$status=$row['print_status'];
if($status==0)
{
?>
<a href="javascript:popWindows('print2.php?rid=<?php echo $row['id']; ?>&pid=<?php echo $_REQUEST['pid'];?>','_winName','1000','1000','scrollbars=1')" style="color:#2A9F00; font-size:12px;">
<?php
echo "Print";
echo "</a>";
}
else
{
?>
<a href="javascript:popWindows('print2.php?rid=<?php echo $row['id']; ?>&pid=<?php echo $_REQUEST['pid'];?>','_winName','1000','1000','scrollbars=1')" style="color:#2A9F00; font-size:12px;">
<?php
echo "Already printed";
echo "</a>";
}
?>
By the way, try using the code tags, and try posting the error(s) you get =)
Best wishes
//AngelicS